Jul 30, 2011 11:21 PM EST

Carrie-Anne Moss Cast in Chuck

Carrie-Anne Moss, known best for her "Matrix" role, has signed on to guest star in the upcoming final season of "Chuck".

Moss will play Gertrude Verbanski, "a former spy who now runs Verbanski Corp, the chief rival of Chuck's new spy company. She's ruthless and deadly, yet she also has a weak spot for one John Casey - her old rival."

Mark Hamill and Craig Kilborn will also be guest starring on the show, both playing villains.

"Chuck", which airs on NBC, will be ending its run with their fifth season, comprised of 13 episodes.  

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